There's no ethanol content PID for these Gen3 3.5's that I know of, but there is an OAR PID, which can at least let you know you are getting good anti-knock.
Hopefully I'm wrong and a PID guru shows up and we can pick his brain.
I have the OAR and KS ones already. I have read where it has it because the 5.0L 21+ trucks are flex fuel again. The PID is in the 3.5L EcoBoost ECM'S and it will function same as in a 5.0 truck but just needs to be enabled.